Addition, Elimination and Substitution: Markovnikov, Zaitsev and Hofmann Rules and the Walden Inversion Books

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Addition Elimination and Substitution Markovnikov Hofmann Zaitsev and Walden


Addition  Elimination and Substitution  Markovnikov  Hofmann  Zaitsev and Walden
  • Author : David E. Lewis
  • Publisher : Elsevier
  • Release : 2021-06-15
  • ISBN : 0128210273
  • Language : En, Es, Fr & De
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Addition, elimination and substitution are foundational reactions in organic chemistry. Addition, Elimination and Substitution: Markovnikov, Hofmann, Zaitsev and Walden: Discovery and Development discusses the major protagonists in these reactions and their major contributions to synthesis. It provides an overview of the history of these reactions. Hofmann, Zaitsev, and Markovnikov are introduced with a biography detailing their major discoveries and contributions to organic chemistry. The history of the controversies around Markovnikov's Rule are addressed, and the author will provide his perspective on the question. The book introduces Walden's original demonstration of configuration inversion, discusses bimolecular elimination reactions, regioselective addition reactions and regiospecific alkene synthesis, and the development of modern reactions with configuration inversion. With its unique perspective, focus and comprehensive coverage, this book belongs on the shelf of every organic chemist. Introduces Markovnikov, Zaitsev, Hofmann and Walden as actual persons, rather than just an abstract term used as a form of short-hand to describe the rules Discusses, in depth, the discovery and usage of these reactions and rules since their discovery to their most recent applications Includes biographical materials about chemists responsible for major changes in the application of the rules Traces the history of the applications of these reactions (e.g., anti-Markovnikov additions in catalytic organic synthesis, and reactions such as the Mitsunobu reaction improving the original SN2 displacement)

Stereoelectronic Effects


Stereoelectronic Effects
  • Author : Igor V. Alabugin
  • Publisher : John Wiley & Sons
  • Release : 2016-10-17
  • ISBN : 9781118906347
  • Language : En, Es, Fr & De
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The molecular world is defined by interactions between electronic orbitals described at increased levels of theoretical sophistication. This book translates these theoretical ideas into the language of practicing organic chemists by illustrating how stabilizing electronic orbital interactions can be maximized by favorable orbital interlap at a particular geometry. This dependence gives rise to the concept of stereoelectronic effects, the ubiquitous forces that define interactions between different molecules and between different parts of a single molecule. This book offers practical guidelines for the control of chemical structure and reactivity. It provides a critical analysis of stereoelectronic effects, including theoretical and experimental approaches to their detection and quantification. It showcases the variety of organic reactivity patterns and explains individual idiosyncrasies and chameleonic behavior of functional groups.

Organic Reaction Mechanisms


Organic Reaction Mechanisms
  • Author : Michael Edenborough
  • Publisher : CRC Press
  • Release : 2017-12-21
  • ISBN : 9781482295344
  • Language : En, Es, Fr & De
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This text is designed to teach students how to write organic reaction mechanisms. It starts from the absolute basics - counting the numbers of electrons around a simple atom. Then, in small steps, the text progresses to advanced mechanisms. the end, all the major mechanistic routes have been covered. The text is in the form of interactive sections, which are designed to facilitate the assimilation of the information conveyed, so that by the end the student should already know the contents without the need for extensive revision.

Reactions Rearrangements And Reagents


Reactions Rearrangements And Reagents
  • Author : Sanyal
  • Publisher :
  • Release : 2019
  • ISBN : 8177096052
  • Language : En, Es, Fr & De
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The Wolff Kishner Reduction and Related Reactions


The Wolff Kishner Reduction and Related Reactions
  • Author : David E. Lewis
  • Publisher : Elsevier
  • Release : 2019-07-20
  • ISBN : 9780128165201
  • Language : En, Es, Fr & De
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The Wolff-Kishner Reduction and Related Reactions: Discovery and Development offers a detailed discussion of this reaction, its discoverers, and its development since its discovery. Derivative name reactions—including the Wharton and Shapiro reactions—are also discussed. The book is illustrated with examples from literature and corresponding references to the primary literature to aid further reading. It provides a comprehensive review of the century of chemistry that allows the reader to follow the development of this important synthetic reaction. In addition, it provides biographical details on the chemists who discovered and developed the reaction, thus adding a human dimension to the discussion. Introduces Wolff and Kishner, the discoverers of the reaction, along with Huang Ming-Long, the developer of an important modification of the reaction Discusses the discovery of the reaction and the way that priority for the discovery was settled between Wolff and Kishner Discusses, in depth, the development and usage of the reaction over the century, from its discovery, to its most recent applications and modifications in synthesis Includes biographical materials on the chemists responsible for major derivative name reactions based on the Wolff-Kishner reduction