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Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis


Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis
  • Author : S. Ted Oyama
  • Publisher : Elsevier
  • Release : 2011-10-13
  • ISBN : 0080558011
  • Language : En, Es, Fr & De
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The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst development. The similarities and distinctions between the different reaction systems are compared, and the latest advances are described. * Comprehensive listing of epoxide products * Broad comparison of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and biological catalysts * Analysis of the general strengths and weaknesses of varied catalytic systems * Detailed description of the mechanisms of reaction for classical and emerging catalysts

Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis


Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis
  • Author : S. Ted Oyama
  • Publisher : Elsevier
  • Release : 2011-10-13
  • ISBN : 0080558011
  • Language : En, Es, Fr & De
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The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions of tons per year to a few grams per year. The diversity of catalysts is large and encompasses all the known categories of catalyst type: homogeneous, heterogeneous, and biological. This book summarizes the current status in these fields concentrating on rates, kinetics, and reaction mechanisms, but also covers broad topics including modeling, computational simulation, process concepts, spectroscopy and new catalyst development. The similarities and distinctions between the different reaction systems are compared, and the latest advances are described. * Comprehensive listing of epoxide products * Broad comparison of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and biological catalysts * Analysis of the general strengths and weaknesses of varied catalytic systems * Detailed description of the mechanisms of reaction for classical and emerging catalysts

Development of Homogeneous and Heterogeneous Epoxidation Catalysts Using Simple Mn II superscript Complexes and Peracetic Acid


Development of Homogeneous and Heterogeneous Epoxidation Catalysts Using Simple Mn II   superscript  Complexes and Peracetic Acid
  • Author : Andrew J. Murphy
  • Publisher :
  • Release : 2005
  • ISBN : STANFORD:36105119732472
  • Language : En, Es, Fr & De
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Vanadium Catalysis


Vanadium Catalysis
  • Author : Manas Sutradhar
  • Publisher : Royal Society of Chemistry
  • Release : 2020-11-11
  • ISBN : 9781839160899
  • Language : En, Es, Fr & De
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Vanadium is one of the more abundant elements in the Earth’s crust and exhibits a wide range of oxidation states in its compounds making it potentially a more sustainable and more economical choice as a catalyst than the noble metals. A wide variety of reactions have been found to be catalysed by homogeneous, supported and heterogeneous vanadium complexes and the number of applications is growing fast. Bringing together the research on the catalytic uses of this element into one essential resource, including theoretical perspectives on proposed mechanisms for vanadium catalysis and an overview of its relevance in biological processes, this book is a useful reference for industrial and academic chemists alike.

Industrial Catalytic Processes for Fine and Specialty Chemicals


Industrial Catalytic Processes for Fine and Specialty Chemicals
  • Author : Sunil S Joshi
  • Publisher : Elsevier
  • Release : 2016-04-12
  • ISBN : 9780128016701
  • Language : En, Es, Fr & De
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Industrial Catalytic Processes for Fine and Specialty Chemicals provides a comprehensive methodology and state-of-the art toolbox for industrial catalysis. The book begins by introducing the reader to the interesting, challenging, and important field of catalysis and catalytic processes. The fundamentals of catalysis and catalytic processes are fully covered before delving into the important industrial applications of catalysis and catalytic processes, with an emphasis on green and sustainable technologies. Several case studies illustrate new and sustainable ways of designing catalysts and catalytic processes. The intended audience of the book includes researchers in academia and industry, as well as chemical engineers, process development chemists, and technologists working in chemical industries and industrial research laboratories. Discusses the fundamentals of catalytic processes, catalyst preparation and characterization, and reaction engineering Outlines the homogeneous catalytic processes as they apply to specialty chemicals Introduces industrial catalysis and catalytic processes for fine chemicals Includes a number of case studies to demonstrate the various processes and methods for designing green catalysts